Why do copper vessels lose shine when exposed to air?

Copper vessels lose their shine when exposed to air due to a reaction with oxygen, moisture, and carbon dioxide in the environment. This process forms a greenish layer known as patina, which is primarily composed of copper carbonate (CuCO3​) and copper hydroxide (Cu(OH)2​).

Formation of Copper Oxide: Copper reacts with oxygen in the air to form copper(II) oxide:

  • 2Cu+O2→2CuO2 This forms a dark brown or black layer on the surface.

Formation of Copper Carbonate: Copper oxide then reacts with carbon dioxide and moisture in the air to form copper carbonate, which gives a greenish color:

  • CuO+CO2+H2O→CuCO3â‹…Cu(OH)2 This layer, known as patina, further dulls the copper’s shine.

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